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MATERIAL SELECTION AND INVESTIGATION OF OPERATIONAL PROPERTIES OF SPECIAL CLOTHING FOR PAINTING WORKSHOP WORKERS

Abstract

Workers in industrial painting workshops are chronically exposed to complex chemical environments comprising solvents, isocyanates, epoxy resins, chromium-based primers, and flammable aerosols, generating multi-hazard risk profiles that current general-purpose workwear inadequately addresses. This study presents a systematic experimental investigation of material selection and operational properties for special protective clothing tailored to painting workshop conditions. A quantitative industrial hygiene survey of five painting facilities (n = 87 workers) established that four of seven measured chemical agents exceeded occupational exposure limits (OELs) by factors of 1.44–2.84×, confirming the critical need for effective barrier clothing. Four candidate fabric systems were fabricated and subjected to a comprehensive test battery: polyamide-cotton (65/35) with flame-retardant (FR) finishing; para-aramid (Nomex® III A); polyester-cotton (67/33) with nano-TiO₂ multifunctional coating; and PTFE membrane laminate composite. Testing encompassed chemical permeation (EN ISO 6529), flame resistance (EN ISO 11612), antistatic performance (EN 1149-3), mechanical durability after 50 industrial laundering cycles (ISO 6330), and physiological comfort indices (ISO 11092). The polyester-cotton/nano-TiO₂ system achieved the highest composite score (7.62/10) in an analytically hierarchical process (AHP) weighted multi-criteria analysis, combining adequate chemical resistance (toluene breakthrough time: 35.6 min), superior antistatic properties (surface resistivity: 3.5×10⁷ Ω), good breathability (MVTR: 5,140 g/m²/24h), and cost efficiency suitable for industrial replacement cycles. Para-aramid demonstrated superior protection across all single-hazard criteria but at prohibitive cost for routine garment replacement. The nano-TiO₂ fabric system is recommended as primary material for painting workshop PPE, with para-aramid hybrid construction proposed for high-exposure roles. These findings provide evidence-based material guidance for occupational safety engineers, procurement specialists, and textile manufacturers.

Keywords

painting workshop PPE; chemical permeation; flame-retardant fabric; nano-TiO₂ textile; antistatic clothing; operational durability; AHP material selection; occupational exposure

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References

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